科创中国

将功能化TiO2纳米管(FTNT)均匀分散在聚偏氟乙烯(PVDF)铸膜液中,利用相转化法制备PVDF/FTNT杂化膜,通过扫描电镜(SEM)、接触角测定、过滤实验和污染性测试等研究了其微结构、分离性和耐污染性能等,并考察膜污染后有效的清洗方法.结果表明,添加FTNT的杂化膜具有不同的微结构与性能,当添加1% FTNT时,杂化膜皮层变薄、微孔数增多,并呈现出最优化的水通量、亲水性、耐压性和抗污染能力等,而对腐殖酸(HA)溶液的截留率略有提高.采用0.01 mol/L的NaOH溶液碱洗和太阳光/水的绿色清洗工艺均能实现膜性能的恢复,而采用后者清洗的杂化膜通量恢复率可达到90%以上.

运用数值模拟,研究膜生物反应器中曝气管路布气位置及导流板对反应器内流场分布的影响,并对3种气水比(10:1、15:1、20:1)进行了优化研究.将模拟结果进行比较发现:"对齐"布气优于"间隔"布气;导流板对反应器内流场特性有较明显的影响,导流作用能有效地改善反应器内气含率的分布状况,提高氧传质效率,增大膜面剪切速度.在相同条件下,其平均膜面剪切速度分别是不加导板的"对齐"和"间隔"布气方式的1.5和1.9倍.当气水比为15:1时,各种布气方式反应器内气含率分布均较大,流场内的涡流均非常明显,整个场内形成了循环流动,膜面剪切速度也达到最大.

Layered organic-inorganic hybrids containing bilayer perovsikte (R-NH3)2(CH3NH3)Pb2I7 (where R=C12H25,C6H5C2H4) were synthesized by reactions in solution. The influences of the solvents and the reactant ratio on the structures of the products were investigated. The structures and the properties of the hybrids were characterized using X-ray diffraction (XRD) and ultraviolet and visible (UV) adsorption spectra. For comparing with the bilayer perovskite hybrids in structure and band gap magnitude, the hybrids containing monolayer perovskite (R-NH3)2PbI4 were also synthesized and characterized. The results demonstrate that the thickness of inorganic layer has obvious effect on the tunneling magnitude of the band gap but the organic part can be micro actuator of band gap.

Though the studies of wheel-legged robots have achieved great success, the existing ones still have defects in load distribution, structure stability and carrying capacity. For overcoming these shortcomings, a new kind of wheel-legged robot(Rolling-Wolf) is designed. It is actuated by means of ball screws and sliders, and each leg forms two stable triangle structures at any moment, which is simple but has high structure stability. The positional posture model and statics model are built and used to analyze the kinematic and mechanical properties of Rolling-Wolf. Based on these two models, important indexes for evaluating its motion performance are analyzed. According to the models and indexes, all of the structure parameters which influence the motion performance of Rolling-Wolf are optimized by the method of Archive-based Micro Genetic Algorithm(AMGA) by using Isight and Matlab software. Compared to the initial values, the maximum rotation angle of the thigh is improved by 4.17%, the maximum lifting height of the wheel is improved by 65.53%, and the maximum driving forces of the thigh and calf are decreased by 25.5% and 12.58%, respectively. The conspicuous optimization results indicate that Rolling-Wolf is much more excellent. The novel wheel-leg structure of Rolling-Wolf is efficient in promoting the load distribution, structure stability and carrying capacity of wheel-legged robot and the proposed optimization method provides a new approach for structure optimization.

以聚醚砜(PES)为基质膜材料,利用微图案硅片为模板,通过非溶剂致相分离法(NIPS)制备PES微图案膜,研究制膜条件对膜表面微图案及膜结构、性能的影响,考察图案化前后PES膜的水通量、接触角、孔隙率、拉伸强度性能差异.结果表明,以模板法制得的PES 膜表面呈现规整的微图案,且膜表面微图案的规整性随铸膜液中PES浓度的增加而提高.接触角、孔隙率和水通量测试表明,相对于PES原膜,制得的微图案膜具有较高的接触角和较高的孔隙率及水通量;机械性能测试表明,图案化前后膜的拉伸强度变化不大.

Now the optimization strategies for power distribution are researched widely,and most of them are aiming to the optimal fuel economy and the driving cycle must be preknown.Thus if the actual driving condition deviates from the scheduled driving cycle,the effect of optimal results will be declined greatly.Therefore,the instantaneous optimization strategy carried out on-line is studied in this paper.The power split path and the transmission efficiency are analyzed based on a special power-split scheme and the efficiency models of the power transmitting components are established.The synthetical efficiency optimization model is established for enhancing the transmission efficiency and the fuel economy.The identification of the synthetical efficiency as the optimization objective and the constrain group are discussed emphatically.The optimization is calculated by the adaptive simulated annealing(ASA)algorithm and realized on-line by the radial basis function(RBF)-based similar models.The optimization for power distribution of the hybrid vehicle in an actual driving condition is carried out and the road test results are presented.The test results indicate that the synthetical efficiency optimization method can enhance the transmission efficiency and the fuel economy of the power-split hybrid electric vehicle(HEV)observably.Compared to the rules-based strategy the optimization strategy is optimal and achieves the approximate global optimization solution for the power distribution.The synthetical efficiency optimization solved by ASA algorithm can give attentions to both optimization quality and calculation efficiency,thus it has good application foreground for the power distribution of power-split HEV.

应用粒子图像测速技术(PIV)对膜蒸馏系统热容腔结构参数影响近膜面处的流动情况进行正交试验,考察喷管前端距膜面的距离δ和喷管中心线与热容腔径向夹角β对流场的影响.试验结果表明,合理布置热容腔的结构参数组合可以使膜面冲刷速度增大,对膜面的有效冲刷面积也增大,更好的破坏温度极化和浓度极化,使系统的膜通量增加.对于试验中采用的膜蒸馏系统,最优的结构参数组合是第32组试验,δ1、δ2、δ3,β1、β2、β3的取值分别为4 mm、3mm、4 mm,50°、35°、25°.流量也是试验中一个重要的影响因素,随着流量的增加,膜面处切向速度增大,对膜面的作用力增大,但是在增大系统流量提高切向冲刷速度的同时,应该考虑膜的机械强度.试验为膜蒸馏系统内部流动的深入研究提供了试验数据和测试经验,可为膜蒸馏系统结构设计的改进和膜蒸馏系统效率的提高提供了参考.

选用碳纤维(CF)、玻璃纤维(GF)和高强玻璃纤维(SGF)为增强材料,制作CF,CF/GF和CF/SGF层间组合混杂纤维增强木梁,并对其受弯性能进行了试验研究,同时分析了该木梁的破坏形态和破坏机理,讨论了其荷载-位移特征、极限承载力和延性.结果表明:与单一CF增强相比,合理匹配混杂纤维增强复合材料(HFRP)可显著提高木梁的承载力和延性.提出了HFRP增强木梁的极限承载力计算方法.

用实验室自制的Al2O3中空纤维膜为基膜,以Al2O3粉末分散液和Al粉分散液为原料,用真空抽滤法与浸渍法制备过渡层,再浸涂勃母石溶胶,烧结形成梯度致密化Al2O3中空纤维膜.讨论了梯度致密化Al2O3中空纤维膜的形貌、泡点压力、膜孔径与渗透性能等因素.结果表明,造成膜性能差异的主要原因有:(1)Al2O3粉末与Al粉的熔点差异;(2)真空抽滤形成的滤饼与浸涂形成的吸附层之间的厚度差.同时,所制得的梯度致密化Al2O3中空纤维膜纯水通量为17~2 990 L/(m2·h·0.1 MPa),平均孔径为0.04~0.52 μm.

选择在螺旋卷式反渗透膜元件组件设计中,对影响膜元件使用寿命的抗污染性能及影响膜元件系统运行能耗的工艺参数进行理论模拟实验,并与实际生产运行相结合,得出最优化的设计组合.主要工艺参数为给水流道布宽度、深度、入水角度、及膜元件卷制页数的优化选择,筛选出提高抗污染性能及低能耗、高经济性的膜元件,并对螺旋卷式膜元件的设计起指导作用.