科创中国

介绍了多孔介质流体动力学中颗粒填充床经典模型Ergun方程.在相同压降、相同孔径条件下,借助有限元分析软件ANSYS,模拟了过滤介质颗粒以立方和六方两种最密堆积结构的水渗透速率,从而分析了超高相对分子质量聚乙烯(PE-UHMW)微孔材料烧结成孔时原料粉体颗粒的堆积模式;最后将已测孔径的PDUHMW粉末烧结管的渗流速率与模拟实验进行了比较.结果表明,PDUHMW烧结微孔管中微孔主要是粉体颗粒以六方最密堆积结构形成的.

There have been various theoretical attempts by researchers worldwide to link up different scales of plasticity studies from the nano-, micro- and macro-scale of observation, based on molecular dynamics, crystal plasticity and continuum mechanics. Very few attempts, however, have been reported in ultra-precision machining studies. A mesoplasticity approach advocated by Lee and Yang is adopted by the authors and is successfully applied to studies of the micro-cutting mechanisms in ultra-precision machining. Traditionally, the shear angle in metal cutting, as well as the cutting force variation, can only be determined from cutting tests. In the pioneering work of the authors, the use of mesoplasticity theory enables prediction of the fluctuation of the shear angle and micro-cutting force, shear band formation, chip morphology in diamond turning and size effect in nano-indentation. These findings are verified by experiments. The mesoplasticity formulation opens up a new direction of studies to enable how the plastic behaviour of materials and their constitutive representations in deformation processing, such as machining can be predicted, assessed and deduced from the basic properties of the materials measurable at the microscale.

以脂肪酶N435催化合成了PHS基脂肪族聚酯,研究了反应条件、溶剂及第三单体的引入对聚酯相对分子质量(Mn)的影响.结果表明:反应24 h后产物的Mn较高,Mw/Mn较小;反应温度为80℃时产物的Mn最高;N435以5%用量为最佳;适当增加二苯醚的用量有利于反应进行;丙三醇的加入可生成具有支化结构的聚酯,少量丙三醇、ε-CL和短链二醇的添加可提高聚酯的Mn,CHDM的空间结构不会影响酶催化聚合反应活性.

对1000MW机组低压II转子高速动平衡过程进行了分析,并对动平衡所用设备及转子的平衡方法进行介绍,为今后国内相关百万超超临界机组转子平衡提供参考和借鉴.

Most gait studies of multi-legged robots in past neglected the dexterity of robot body and the relationship between stride length and body height.This paper investigates the performance of a radial symmetrical hexapod robot based on the dexterity of parallel mechanism.Assuming the constraints between the supporting feet and the ground with hinges,the supporting legs and the hexapod body are taken as a parallel mechanism,and each swing leg is regarded as a serial manipulator.The hexapod robot can be considered as a series of hybrid serial-parallel mechanisms while walking on the ground.Locomotion performance can be got by analyzing these equivalent mechanisms.The kinematics of the whole robotic system is established,and the influence of foothold position on the workspace of robot body is analyzed.A new method to calculate the stride length of multi-legged robots is proposed by analyzing the relationship between the workspaces of two adjacent equivalent parallel mechanisms in one gait cycle.Referring to service region and service sphere,weight service sphere and weight service region are put forward to evaluate the dexterity of robot body.The dexterity of single point in workspace and the dexterity distribution in vertical and horizontal projection plane are demonstrated.Simulation shows when the foothold offset goes up to 174 mm,the dexterity of robot body achieves its maximum value 0.164 4 in mixed gait.The proposed methods based on parallel mechanisms can be used to calculate the stride length and the dexterity of multi-legged robot,and provide new approach to determine the stride length,body height,footholds in gait planning of multi-legged robot.

The mechanical properties and microstructure evolution of cold-deformed CrMnN austenitic stainless steel annealed in a temperature ranging from 50 ℃ to 650 ℃ for 90 min and at 550 ℃ for different time were investigated by tensile test, micro hardness test, and Transmission Electron Microscope (TEM). The steel was strengthened when it got annealed at temperatures ranging from 100 ℃ to 550 ℃, while it was softened when it got annealed at temperatures ranging from 550 ℃ to 650 ℃. Annealing temperature had stronger effect on mechanical properties than annealing time. TEM observations showed that nano-sized precipitates formed when the steel was annealed at 150 ℃ for 90 min, but the size and density of precipitates had no noticeable change with annealing temperature and time. Recrystallization occurred when the steel was annealed at temperatures above 550 ℃ for 90 min, and its scale increased with annealing temperature. Nano-sized annealing twins were observed. The mechanisms that controlled the mechanical behaviors of the steel were discussed.

The competition of surface and subsurface crack initiation induced failure is critical to understand very high cycle fatigue(VHCF)behavior,which necessitates the elucidation of the underlying mechanisms for the transition of crack initiation from surface to interior defects.Crack initiation potential in materials containing defects is investigated numerically by focusing on defect types,size,shape,location,and residual stress influences.Results show that the crack initiation potency is higher in case of serious property mismatching between matrix and defects,and higher strength materials are more sensitive to soft inclusions(elastic modulus lower than the matrix).The stress localization around inclusions are correlated to interior crack initiation mechanisms in the VHCF regime such as inclusion-matrix debonding at soft inclusions and inclusion-cracking for hard inclusions(elastic modulus higher than the matrix).It is easier to emanate cracks from the subsurface pores with the depth 0.7 times as large as their diameter.There exists an inclusion size independent region for crack incubation,outside which crack initiation will transfer from the subsurface soft inclusion to the interior larger one.As for elliptical inclusions,reducing the short-axis length can decrease the crack nucleation potential and promote the interior crack formation,whereas the long-axis length controls the site of peak stress concentration.The compressive residual stress at surface is helpful to shift crack initiation from surface to interior inclusions.Some relaxation of residual stress can not change the inherent crack initiation from interior inclusions in the VHCF regime.The work reveals the crack initiation potential and the transition among various defects under the influences of both intrinsic and extrinsic factors in the VHCF regime,and is helpful to understand the failure mechanism of materials containing defects under long-term cyclic loadings.

The remanufacturing blanks with cracks were considered as irreparable. With utilization of detour effect and Joule heating of pulsed current, a technique to arrest the crack in martensitic stainless steel FV520B is developed. According to finite element theory, the finite element(FE) model of the cracked rectangular specimen is established firstly. Then, based on electro-thermo-structure coupled theory, the distributions of current density, temperature field, and stress field are calculated for the instant of energizing. Furthermore, the simulation results are verified by some corresponding experiments performed on high pulsed current discharge device of type HCPD-I. Morphology and microstructure around the crack tip before and after electro pulsing treatment are observed by optical microscope(OM) and scanning electron microscope(SEM), and then the diameters of fusion zone and heat affected zone(HAZ) are measured in order to contrast with numerical calculation results. Element distribution, nano-indentation hardness and residual stress in the vicinity of the crack tip are surveyed by energy dispersive spectrometer(EDS), scanning probe microscopy(SPM) and X-ray stress gauge, respectively. The results show that the obvious partition and refined grain around the crack tip can be observed due to the violent temperature change. The contents of carbon and oxygen in fusion zone and HAZ are higher than those in matrix, and however the hardness around the crack tip decreases. Large residual compressive stress is induced in the vicinity of the crack tip and it has the same order of magnitude for measured results and numerical calculation results that is 100 MPa. The relational curves between discharge energies and diameters of the fusion zone and HAZ are obtained by experiments. The difference of diameter of fusion zone between measured and calculated results is less than 18.3%. Numerical calculation is very useful to define the experimental parameters. An effective method to prevent further extension of the crack is presented and can provide a reference for the compressor rotor blade remanufacturing.

New generation thermo-mechanical control process(TMCP) based on ultra-fast cooling is being widely adopted in plate mill to product high-performance steel material at low cost. Ultra-fast cooling system is complex because of optimizing the temperature control error generated by heat transfer mathematical model and process parameters. In order to simplify the system and improve the temperature control precision in ultra-fast cooling process, several existing models of case-based reasoning(CBR) model are reviewed. Combining with ultra-fast cooling process, a developed R5 CBR model is proposed, which mainly improves the case representation, similarity relation and retrieval module. Certainty factor is defined in semantics memory unit of plate case which provides not only internal data reliability but also product performance reliability. Similarity relation is improved by defined power index similarity membership function. Retrieval process is simplified and retrieval efficiency is improved apparently by windmill retrieval algorithm. The proposed CBR model is used for predicting the case of cooling strategy and its capability is superior to traditional process model. In order to perform comprehensive investigations on ultra-fast cooling process, different steel plates are considered for the experiment. The validation experiment and industrial production of proposed CBR model are carried out, which demonstrated that finish cooling temperature(FCT) error is controlled within ±25 ℃ and quality rate of product is more than 97%. The proposed CBR model can simplify ultra-fast cooling system and give quality performance for steel product.

采用自行合成的单分子膨胀阻燃剂季戊四醇酯三聚氰胺磷酸盐(MPPL)以及混合型膨胀阻燃剂三聚氰胺磷酸盐(MP)/李戊四醇(PEL)阻燃高密度聚乙烯,比较了2种阻燃材料的各项性能指标,研究表明:单分子膨胀阻燃材料体系具有更优异的阻燃性能、机械力学性能以及耐水性.通过热失重测试和炭层形貌表征分析研究了2种体系阻燃性能显著差异的原因.